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Concepts to Remember
Chapter 2: Measurements in Chemistry
The metric system. The metric system, the measurement system preferred by scientists, is a decimal system in which larger and smaller units of a quantity are related by factors of 10. Prefixes are used to designate relationships between the basic unit and larger or smaller units of a quantity. Units in the metric system include the gram (mass), liter (volume), and meter (length).
Exact and inexact numbers. Numbers are of two kinds: exact and inexact. An exact number has a value that has no uncertainty associated with it. Exact numbers occur in definitions, in counting, and in simple fractions. An inexact number has a value that has a degree of uncertainty associated with it. Inexact numbers are generated anytime a measurement is made.
Significant figures. Significant figures in a measurement are those digits that are certain, plus a last digit that has been estimated. The maximum number of significant figures possible in a measurement is determined by the design of the measuring device.
Calculations and significant figures. Calculations should never improve (or decrease) the precision of experimental measurements. In multiplication and division, the number of significant figures in the answer is the same as that in the measurement containing the fewest significant figures. In addition and subtraction, the answer has no more digits to the right of the decimal point than are found in the measurement with the fewest digits to the right of the decimal point.
Scientific notation. Scientific notation is a system for writing decimal numbers in a more compact form that greatly simplifies the mathematical operations of multiplication and division. In this system, numbers are expressed as the product of a number between 1 and 10 and 10 raised to a power.
Dimensional analysis. Dimensional analysis is a general problem-solving method in which the units associated with numbers are used as a guide in setting up calculations. A given quantity is multiplied by one or more conversion factors in such a manner that the unwanted (original) units are canceled, leaving only the desired units.
Density. Density is the ratio of the mass of an object to the volume occupied by that object. A correct density expression includes a number, a mass unit, and a volume unit.
Temperature scales. The three major temperature scales are the Celsius, Kelvin, and Fahrenheit scales. The size of the degree for the Celsius and Kelvin scale is the same. They differ only in the numerical values assigned to the reference points. The Fahrenheit scale has a smaller degree size than the other two temperature scales.
Heat energy. The most commonly used unit of measurement for heat energy is the calorie. A calorie is the amount of heat energy needed to raise the temperature of 1 gram of water by 1 degree Celsius.
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